- Easier storage. Wood has to be kept off the ground, covered from the elements, and neatly stacked to provide airflow for drying. You'll only bring in what you need to burn for a day in order to cut down on the pests and debris inside. Charcoal can be stored in a box, bag, or bin about anywhere until you need it. You'll have black dust instead of bits of bark, splinters, dirt, bugs, and other debris once you empty a storage space.
- Longer storage life. Wood rots. Insects and vermin love woodpiles, as they provide shelter and food for them until they get a chance to move into your living quarters. Unless you are very careful with your storage, raw wood will only last a few years before it has degraded to a state where it's not usable as fuel. Charcoal, however, is close to coal in shelf-life, and without the water and volatile elements of wood, insects and vermin have no resources to exploit so it won't degrade as quickly. It is a bit more fragile than wood, so repeated handling will result in smaller pieces, but they'll still burn at the same rate.
- Higher burning temperature. Pure carbon like coal or charcoal can burn at a higher temp because of the lack of water. Water takes a lot of heat to turn into vapor, and that heat is then not available for cooking or heating. Charcoal doesn't burn quite as hot as coal so it's safer to use in woodstoves.
- More efficient. During the production of charcoal, the voids or empty spaces created by the removal of water and volatile elements form channels for combustion. This makes for a more uniform burn in a smaller space, which makes it easy to have a more efficient fire.
- Cleaner burning. If you're smoking or drying meat for preservation, wood will impart a taste or flavor to the meat. Sometimes that is the desired effect; the use of hickory, mesquite, apple, etc. wood to impart a flavor is common, but if all you have available are cedar, pine, or some other wood with a disagreeable taste, you'll end up making dried food that not even the dogs will eat. The process of making charcoal removes all of the volatile compounds that will provide flavor, so the source wood isn't a factor. You'll end up with about the same amount of ashes as wood, but without the clinkers that coal will produce.
- More uniform heat generation. Wood is never uniform, so you're going to have differing heat coming from different spots at different time as it burns. Look at the end of a log and you'll see the variations in quality of fuel: bark, soft outer layers, harder inner layers, knots, rot, etc. Charcoal production takes away most of the variations, leaving a more uniform fuel for a more uniform fire.
- Higher energy density. Since charcoal doesn't have the impurities found in wood, you can get about three times the heat out of a pound of charcoal versus a pound of wood. While less dense than wood, the higher energy content per pound of charcoal makes transportation more efficient as well. For a scholarly explanation of the numbers, here's a report out of Africa comparing the two. Reading through examples from areas that lack our infrastructure is a good source of ideas for how to deal with the failure (or lack of) said infrastructure.
Thursday, November 11, 2021
Charcoal, Part 1: Fuel
Friday, February 19, 2021
Bad Gas
If your fuel is in a gas can, the fix is even simpler: just dilute it with good gas. A ratio of 10:1 or better will burn just fine, and shouldn't harm an engine in good repair. Running a higher ratio like 15:1 will burn your bad fuel slower, but will burn easier in your engine, if you're worried. For clarification, that means 10 or 15 gallons of good gas to every 1 gallon of old fuel.
You can also run old fuel in gasoline yard tools, diluted with good fuel. The ratio can be a bit shorter in gasoline tools, as low as 5:1, since their engines are simpler with fewer places that can get gummed up and minimal electronics to be affected.
Prevention is always the best course. Rotate your fuel stocks and use fuel stabilizers whenever possible. If all else fails and you find yourself with some old gas, you haven't lost that money or that resource; hit it with fuel conditioner or dilute it with good fuel and carry on.
Lokidude
Thursday, December 17, 2020
Diesel Treatment for Cold Weather
Cold Weather Diesel Problems
Once it gets cold enough, diesel fuel will "gel", meaning that the components of the fuel will solidify and fall out of suspension. Normal #2 diesel has a fair percentage of paraffin wax as a component which solidifies easily. Solid wax doesn't flow, so fuel lines and filters tend to get blocked and fuel pumps have a hard time moving it through the injectors. This means that a cold diesel engine won't start or won't stay running once the fuel starts to gel.
The exact temperature of "cold enough" will vary with the grade of fuel, so in the winter most sellers will either switch to the more expensive, wax-free, #1 diesel (kerosene), or they will blend their #2 diesel about 60/40 with #1 diesel to keep the price down while still being able to pump it.*
Lets look at a few of the problem points of #2 diesel.
Cloud Point
At about 32°F, diesel fuel starts to get cloudy due to the wax starting to form solid crystals. Cloudy fuel will flow through pumps and pipes, but will start to plug filters unless those filters are kept warm. Engine efficiency will suffer and fuel mileage will drop because the fuel system is struggling to move enough fuel.
Cold Filter Plug Point
Since a fuel filter is designed to trap particles, once the wax starts to solidify it will get trapped in and blind off the filter. #2 diesel hits this point at about 15°F and engines start to stall... if they'll start at all.
Pour Point
Once the temperature drops down to 0°F, the wax will have gelled to a point that the fuel will no longer flow (or pour). No fuel means an engine will not run.
The red bottles are Power Service 911, and that is used to fix already gelled fuel. The normal method is to remove the fuel filter and pour the 911 into the canister, where it can dissolve the congealed wax and allow fuel flow. The rest of the container, or another one, is dumped into the fuel tank and left to sit for an hour or two so it can do the same to the fuel there.
The clear bottles of brown liquid are Howes Diesel Treat, our best seller. Howes does everything that the Power Serve does, but backs it up with a guarantee that if you run six bottles of it through your equipment and it still gels, they will pay for the tow to get you fixed up. The two-quart bottles shown will treat up to 320 gallons of fuel, which is easier to use in storage tanks and commercial vehicles with large fuel tanks.
If you have a diesel generator or vehicle, winter can make life more difficult. Keep them warm if you can and treat your fuel so they will start when you need them.
* As a point of interest, home heating oil is basically #3 diesel and has even more wax content. This provides more heat per gallon, but gels up faster if unheated.
Friday, February 8, 2019
Old School Gas Can Hack
Friday, October 20, 2017
Bugging In: Fuels and Storage
Thursday, April 13, 2017
Pump It Up
What Is a Pump?
A pump is a mechanism for moving a fluid (gas or liquid state) from one area to another. Both a trash pump and your heart are liquid pumps, but they work by different methods and are examples of the two main types of pumps.
Centrifugal pumps
Centrifugal pumps work by using a spinning disk, usually one with vanes on its face, to throw the fluid against a casing that directs the flow in the desired direction. Normally the intake is in the center of the disk (called an impeller) and the discharge is rotated 90° from the intake. Here's a simple example :
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| Image #1 |
If you have a well, you probably have a submersible centrifugal pump at the bottom. Your water-cooled vehicle has a centrifugal water pump that moves the coolant through the engine and radiator. The fuel pump in newer (fuel injected) cars is a centrifugal pump. Centrifugal pumps are very common in industry.
Pros
- Easy to work on: as long as you have the correct seals on the drive shaft, the pump will run for years and parts are not built with excruciatingly tight tolerances.
- Long life: because the impeller and volute are not actually touching each other, there is very little wear between the two.
- Variable rates: by changing the speed of the drive shaft, you can easily change the rate of flow (within reason). There is a minimum speed below which the pump won't move anything, and a maximum speed where the spinning parts will fail, but there is a range of flow rates from a single pump.
- Tolerant of variable feed: properly designed, they can handle a limited amount of solids mixed in with the fluid feed. Liquid pumps will handle a limited amount of gasses in the feed.
- Good for pushing fluids long distances and up high vertical distances (AKA "head").
- Dead-head resilient: If the discharge is blocked, the pump will not build up much pressure. This is handy if you can't, or don't, want to deal with high pressure lines.
- High flow rates at lower pressures: I used to work with pumps that had up to 18,000 gallons per minute flow rates, but they were only working against about 6 feet of vertical head -- about 3 PSI.
- No dry start: the volute must be full before the pump will work. So-called "self priming" pumps simply have a method of filling the volute before starting the pump, or they have a volute that is designed to hold fluid after power is shut down.
- Poor suction: while they are capable of generating moderate discharge pressures, they won't suck up anything below the inlet port.
- Lower efficiency: only about 60% of the energy put into the pump is transferred to the fluid. There is a method of figuring out peak efficiency, but I don't want to get into how to read a pump curve in this post.
- Works best with thin fluids: oils and greases are too viscous to be moved through a centrifugal pump.
Positive Displacement Pumps
Unlike centrifugal pumps, positive displacement (PD) pumps use a wide variety of methods of moving fluids. They all have two things in common: check valves, and a chamber that changes in volume. The check valves may not be separate pieces, or they may be an integral part of the mechanism, but there has to be some way to prevent back-flow for a PD pump to work.
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| Image #3 |
This is a peristaltic pump, commonly used as a "metering" pump because the volume of fluid is set by the size of the tubing. By changing the speed of the drive, you can easily meter out exact amounts of fluid. The changing volume is in the tubing, and the check valves are formed by the rollers as they pinch the tubing against the housing. They're easy to work on since the great majority of any wear is in the tubing, which is easily replaced.
| Image #4 |
Pros
- Often self-priming: they are designed to move gasses as well as liquids, so they can prime themselves from a dry start. A pitcher pump may need a cup of water dumped down the casing to wet the leather piston to form a good seal, which is why you'll sometimes find a full water jar next to the hand pump.
- Good for thicker fluids: high viscosity liquids like oil and grease are no problem for a PD pump. I've seen specialty PD pumps that will move wet concrete through a hose to the building site.
- High pressure: the common pressure washer that you use to clean your sidewalk or power-wash your siding uses a piston pump. Pressures in the thousands of PSI are easy to achieve with a PD pump.
- High pressure: if the discharge gets blocked, most PD pumps will create dangerous levels of pressure in a matter of seconds. I've seen someone close the wrong valve and have to clean up after a 6" diameter pipe blew out.
- Touchy to work on: much tighter tolerances in the manufacture means that PD pumps tend to be harder to work on, especially in the field. Special "clean rooms" are normally set aside for working on PD pumps to keep dust and dirt out of the internal parts.
- Lower flow rates than centrifugal pumps.
- Shorter life-span than a centrifugal pump: the tighter tolerances and constant motion of parts against each other lead to increased wear.
So picking a pump is not as easy as it seems. Like most of life, there are compromises and trade-offs in deciding which pump to choose if you're trying to empty a UST. I'm still doing some research and will update last week's article soon. Unfortunately I haven't been able to find a gas station that will let me field test any of my possible solutions; for some reason they're not fond of anyone spreading information that could help thieves...
- https://blogger.googleusercontent.com/img/b/R29vZ2xl/AVvXsEj4ejOGvbeD7cILWxqg7X8R_efrKQ4Jlq0Rts5BW2fQccMA1MYXwxqAGwIve6HYuopk3Vh0DKQ43fKAEaBcjpIekHJMVBZ8f37KQ5TYAgFfiw8ro8agY1QeXPdzOm7bVkZ4aNaEEcV32Hyt/s1600/animatedcentrifugalpump.gif
- https://upload.wikimedia.org/wikipedia/commons/thumb/6/69/Hand_Pump_-_Animation.gif/220px-Hand_Pump_-_Animation.gif
- http://www.ipumps.biz/i-Pumps2.gif
- http://www.gmpumpsa.com/wp-content/uploads/2014/01/Proc201_010100_G08.gif
Thursday, April 6, 2017
Got Gas?
Gas stations don't normally have back-up generators, but they do have underground storage tanks full of fuel.
Anatomy of a UST
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| http://www.kiwimill.com/wp-content/uploads/2013/11/IMG_4537.jpg |
This is a generic model of an underground storage tank (UST). The American EPA made drastic changes to the laws covering USTs back in 1988, requiring that existing tanks meet new standards or be replaced with new tanks that met the standards. Most of the tanks you'll find in the US will be laid out similar to the picture, so I'll use it to point out how to access the fuel in the tank if the pumps are dead.
- Vent pipe
- Fill pipe
- Fuel pump
- Meter (AKA gas pump or island)
Last, and most important, is the fill pipe. You've probably driven over the fill pipe connections dozens of time without even noticing them -- they're the bumps in the driveway near the islands. Here's a picture of a common fill point.
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| Photo credit: Chaplain Tim |
They are about 10 inches in diameter and normally raised an inch or two above the surface to keep rain water out. The lid will be heavy so it will stay in place with cars driving over it.
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| Photo credit: Chaplain Tim |
A simple lock is all that secures the cap, but remember that you're working on a fuel tank, so don't use anything that will create a spark to remove the lock!
After the lock is off, simply lifting up on the ring, or ears of the latch, unlatches the cap and it lifts off with ease. The ring is supplied to make it easier to remove the cap while wearing heavy rubber gloves, a safety measure for the guys who handle fuel for a living.
Once you have the cap off, you'll have a three-inch or better pipe running straight down to the fuel. Getting the fuel out will require a pump and some hose or pipe.
Diesel is a lot safer to work with (it has a higher flash point than gasoline), so pumps rated for diesel are easier to make and thus cheaper. Finding a pump rated to transfer gasoline is neither simple nor cheap, and finding one that can lift liquids more than a few feet makes the search even harder.
Since you're trying to lift a liquid up out of a tank, a siphon isn't going to work. Centrifugal pumps require a full pump before they will work, so unless you have a way to “prime” your pump they are a poor choice; what you are going to need is a “positive displacement” pump of some sort. For shallow tanks that are mostly full, any of the pumps rated for gasoline with a suction “head” rating of at least 8 feet will work.
Getting the last few feet out of a UST will take a submersible pump dropped into the tank, and that is a DIY project that I could piece together from a spare automotive fuel pump and some extra wire. The fuel pump in your car is likely inside the gas tank, so they're designed to be submerged, the hard part would be sealing the wiring up to avoid any possibility of sparks.
This is a subject that requires more research, I will be coming back to it and posting an update.
Pipe/Hose
The small station I help take care of has three 5,000 gallon tanks underground that get topped off about once a week. Larger stations that do a lot more business will have more and larger tanks, and get resupplied more often.
This information is provided for informational and educational purposes only. The author assumes no liability in how you use this information and cannot be held responsible for your actions.
Sunday, December 4, 2016
Gun Blog Variety Podcast #120 - Your Life is a Kitchen
- Beth brings her husband Sean (not GBVC Sean, a different Sean) back on to talk about being a couple who shoot competitively.
- A 32-year-old woman is accused of stabbing her 61-year-old former roommate to death. Sean takes a closer look.
- Barron is on assignment and will return soon.
- In the Main Topic, Sean and Erin answer a pair of questions from a liberal gun-owning listener: "What do you hear when a liberal says 'We need to have a conversation', and what do you hear when a liberal says 'We need to compromise' ?"
- In a late night/early morning segment, Tiffany discusses the First Amendment concept of "fighting words" and how that relates to your Second Amendment right to armed self-defense.
- When the oil from the hurricane lamps you've got stored in the garage leaks all over the floor, how can you get it cleaned up? Erin gives you some tips.
- Massachusetts Attorney General Maura Healey is back, this time in a Vice News interview. You know what that means: it's time for another patented Weer'd Audio Fisk™!
- Our plug of the week is for Roll20.
Thanks also to Firearms Policy Coalition for their support.
We maintain several hurricane lamps in the house for, not surprisingly, if we lose electricity from a hurricane. And we’ve had these lamps for a long time -- at least 30 years now.
Now despite these lamps being old they haven’t received a lot of use, because storms rarely knock out electricity for more than a few hours and because (with my help) my family has moved on to battery-powered means of long term light.
But batteries can wear down, and it’s always good to have backups, so we’ve kept these lamps around. However, the drawback to owning one is that you also need to stay well-stocked with lamp oil.
Now I don’t know if our listeners know this -- I certainly didn’t until this past week -- but apparently the plastic bottles that store lamp oil can become brittle after, oh, a decade of storage in a garage, and past that point bumping them, or even moving them, will cause them to crack (or in our case, shatter) and leak all over the place.
So this past week has involved me asking the collective wisdom of the Blue Collar Prepping Facebook Group -- if you aren’t a member, you’re wrong, join today -- how to clean up the stinky stain in my garage and if there’s any hazard associated with it.
So first of all, lamp oil is just highly refined kerosene, with a flash point -- that means “the temperature at which it ignites” -- of 363 degrees F. This is not to be confused with the auto ignition point, which means “the temperature at which it spontaneously ignites without needing a spark”, and is a much higher 428 degrees F.
These are all good things to know, because it means that the spill won’t catch fire in a hot garage!
So, onto the cleanup, and the techniques I outline here can be used for other forms of fuel, like gasoline.
The first thing I need to do it absorb as much of the oil as possible. This is best done with clay-type non-clumping cat litter, although dry sand will also work. Cover the stain with it, wait until it’s saturated, then dispose of the litter or sand and replace it. I need to keep doing this until there’s no more oil to be absorbed, and if I really want to get aggressive I can scrub the litter into the floor with my shoe or a broom.
After that, I’m going to spray the stain with carburetor cleaner. This is supposed to “lift” any remaining oil out of the concrete and allow it to be absorbed as disposed of.
I need to spray the stain until it’s covered -- not a thick coat, just wetted down -- let it stand about 5-10 minutes, then put more kitty litter onto it. I’m told that I should repeat this about 3 more times. This will probably get out everything it’s possible to get out.
After THAT, I need to use Dawn dishwashing soap to break down whatever oil is left and cause it float to the top. More kitty litter!
After that’s done, it’s just a simple matter of washing off the rest of the Dawn with water and a mop.
Of course, all of this trouble could have been avoided if I’d prevented the lamp oil from spilling in the first place. What I’m going to do to keep this from happening in the future is to keep our remaining bottles of oil in a big plastic storage tub. That way, even if the bottles break, the only mess will be inside the tub instead of all over the floor!
Monday, September 19, 2016
Fuel Storage
Storing fuel for your vehicles and generators breaks down into two parts: safety and treatment.
- Never store gasoline inside an inhabited building! Gasoline is more volatile than diesel, and the vapors are heavier than air so they can travel along a floor to an ignition source. A fan motor starting, a pilot light on a water heater, or a light switch being flipped can cause a huge explosion.
- Keeping air away from the fuel is the first step to storage. Containers must be airtight, preferably without a separate vent hole to reduce the chances of air getting inside and vapors getting out.
- Fuel containers are color-coded: Red for gasoline, yellow for diesel, blue for kerosene. Don't mix them up unless you want to destroy an engine or two.
- Metal containers are better than plastic. Metal seals better and is more durable than plastic, but it costs more.
- Have fire extinguishers close to anywhere you are storing fuel. You're not likely to be able to put out a fuel fire, but you might be able to prevent a small fire from reaching your supply.
- Keeping the fuel cool and at a constant temperature is the best way to store it. You're not going to be able to store gasoline below its vapor (or flash) point (-77° F), but you'll reduce the condensation inside the containers. Diesel,with a flash point around 105° F, is a lot easier to store.
- Minimizing vapors means less of a chance of accidental fires and explosions.
- Large containers (over 5 gallons) are easier to deal with safely than small ones. Having a 55 gallon drum or 100 gallon transfer tank leads to fewer vents and spills. It is also easier to keep track of when it is time to rotate your fuel when it is all in one place.
- Transfer tanks and pumps are designed to be carried in the back of a pickup and have stringent DOT and other government regulations. Be careful if the rule of law is still operating, and do your research; I have a CDL with a Haz-Mat endorsement so I can get away with a bit more than most people, but it comes at a cost.
- Sta-Bil is the most common, and will work for a gasoline stored for up to a year. Re-treating every year seems to maintain the stability of the fuel for several (up to an indeterminate number of) years. I've used Sta-Bil in my lawnmower gas for years and have never had it go bad over a winter, so I can testify to at least 8 months of effectiveness.
- Sea-Foam is more of a cleaner than a stabilizer, but it will help refresh old gasoline that wasn't treated and provides some protection for stored gasoline. The marine grade gets better reviews than the standard grade.
- Several 2-stroke oils have stabilizers added. From what I've found, they seem to work as well as Sta-Bil.
- PRI makes PRI-D for diesel and PRI-G for gasoline. They are industrial suppliers that specialize in fuel treatment for marine and heavy industrial customers, so their retail footprint is small. Their products are in use in large ocean-going vessels and fuel tanks for back-up generators at nuclear power plants, something I consider a good endorsement of their efficiency. The bottles are more expensive but treat a lot more fuel, so compare unit prices before buying.
- There are several “enzyme” treatments that claim to be able to revitalize stale gasoline, but the jury is still out on how effective they are. Anecdotal evidence becomes “He said, she said” before the truth is ever known. Several of these products haven't been on the market long enough to back the claims they make, which tends to raise the reading on my BS meter.
Gasoline and diesel are not designed to be stored long-term.
Freshness
- As sold at the pump, gas is going to stay “fresh” for about six months and diesel for about a year.
- Both will slowly oxidize from contact with the air and lose their combustibility.
- Both will absorb moisture from the air if they are exposed to it. Ethanol-blend gasoline is worse in this regard.
- Water is denser than diesel or gasoline and will settle to the bottom of any container.
- Water in diesel leads to biological growth of bacteria that will foul filters and block lines.
- Diesel tends to form gummy deposits that will plug filters and injectors.
- Gasoline will also form gums and varnish that will plug a carburetor and injectors after storage.
- Both will cause carbon (soot) build-up inside an engine after sitting for a long time, which reduces an engine's power and makes it run rough.
My Setup
I keep a few 5 gallon cans of gas on hand for emergencies and rotate them through the lawnmower and chainsaws. I have used Sta-Bil for years and never had a problem, but it rarely sits for more than a year. It seems like I'm always running into someone who has run out of gas, or some other need pops up, and the stored gasoline gets used and replaced before the year is up.
Thursday, August 11, 2016
Unconventional Chainsaw Oils
Older engines (pre-1970) were designed to run at lower speeds and used common motor oil (non-detergent 30W) in the fuel/oil blend at ratios of 20:1 or more. While motor oil might work on newer engines, it will likely cause excessive wear and shorten the life of the engine. Vegetable oils are the same: they will work for a short time but are not going to give the lubrication that the engine needs.
- RC (radio controlled) airplanes use tiny 2-stroke engines with a high-energy fuel.
- Chainsaws and weedeaters use slightly larger engines and common gasoline.
- Certain racing motorcycles use large 2-strokes, as do snowmobiles and personal watercraft.
Thursday, May 5, 2016
Propane
Propane is a gas at normal temperatures, but can be easily compressed into liquid form easily. It boils at -44° F, so it must be handled with care to prevent frost-bite. Unlike natural gas (methane), propane is heavier than air and it will settle into low areas of a structure if there is a leak. Since water heaters and furnaces tend to have their igniters near the floor, this can cause explosions capable of lifting a house -- if not destroying it completely.
Ventilation and checking for leaks is the key to preventing fires and explosions. Do I really need to explain that propane is flammable and you shouldn't smoke around it? No open flame or fire within 50 feet of open propane source, please. We don't need to hear about you on the nightly news.
Refilling Disposables
Did you know that you can refill disposable 14-16 oz cylinders? There are fittings available to let you refill them from a 20 lb cylinder as often as you need. (Read the instructions and follow them. And wear good gloves, preferably insulated rubber gloves; getting bare skin sprayed with liquid propane at -44° means instant frostbite.)
Refilling From a Tank
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| http://www.ncagr.gov/standard/LP/LPgasConcerns/cylindervalves.htm |
A simple method of refilling a 20 lb cylinder from a large tank:
- Put on your gloves.
- Connect hose to tank discharge valve, usually Acme threads.
- Connect hose to cylinder valve.
- Open cylinder valve and slightly open cylinder vent (fixed level gauge).
- Slowly open tank discharge valve.
- Step back and wait.
- Once liquid starts coming out of cylinder vent, close valves and vent and disconnect hose.
Thursday, April 21, 2016
Chemistry for Preppers: Distillation
How It Works
Distillation is a method of separating mixed chemicals based upon their boiling points (BP). If the difference in boiling points is more than roughly 25° C a simple still will work, but if the difference is less than 25° C you'll need to look into fractional distillation. The boiling points for various chemicals can be found in most chemistry reference books as well as the ubiquitous Material Safety Data Sheets (MSDS or SDS) that producers are required to make available for every product they handle.
There are mixtures that cannot be separated by use of a still. If the boiling points are too close to each other, or if they form an azeotrope (a mixture where the BP of the mixture is higher or lower than either of the constituents), you will not be able to get complete separation from a still. Be careful if dealing with petrochemicals or explosive compounds as they may decompose (violently) when heated, long before they reach boiling point.
If you are distilling anything for consumption, use only food-safe material in the construction of your still. Galvanized metal and lead-based solder will impart toxic levels of metals into your product. Stick with glass, copper, or stainless steel if at all possible.
Bottoms: The material left over after you have distilled out what you want.
Condenser: A pipe or passage that acts as a heat exchanger to cool the vapors back into liquid phase. The common moonshiner's term for a condenser is “worm”, since they use coiled copper tubing that looks like a snake or worm. For cooling fuel-grade alcohol an old car radiator would work, but the metals present would make the distillate unsafe to drink. Running cold water over the exchanger will make it more efficient, but simply moving air past it will also work.
Fractioning Column: A vertical column rising above the pot, fitted with trays or packing. (Explanation below) Fractioning columns will often have more than one outlet, to allow the collection of parts of complex mixtures like crude oil.
Thump Tub: An intermediate cooling stage commonly found in moonshine stills. Vapor from the top of the pot is passed over a container of water on its way to the condenser. This allows for the removal of some of the chemicals that can impart bad flavors to drinking alcohol.
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The trays are designed to allow the heated vapors to rise through the column, but the “caps” on the holes in the trays cause some of them to condense at the temperature present at that height. The condensed liquid helps maintain the temperature at that height and is drawn off in a continuous stream.
Fractional distillation would be useful for long-term situations as a way to recycle used motor oil or production of fuel from local supplies of crude oil (which is more common that you may believe, I've seen oil wells in Iowa and Nebraska). By using a taller tower with more trays, it would be possible to sort out the constituent parts of the gasses produced by roasting coal or wood to produce fuels and solvents such as methanol (wood alcohol) and acetone.
There is also a lot of research going on right now into the recycling of waste tires and various biological wastes into crude oil through pyrolysis. If we ever get to the Mad Max stage of survival, knowing how to produce lubricating oils and fuel could be a valuable skill.
Thursday, August 27, 2015
Trade Goods: Alcohol
One of the topics that got brought up was trade goods. Food, medicine, clothing, tobacco, and ammunition were all mentioned, but I got a few questions about alcohol. Useful as a fuel, antiseptic, for recreational use, or just as a way to store value, alcohol can be a handy thing to have around. It can be even more handy to know how to make it.
First things first: Fuel alcohol is not and cannot be made safe to drink. Drinking alcohol may be usable as fuel, but it doesn't go the other direction. Fuel alcohol is made using materials and methods that can contaminate it with poisonous chemicals, and by law it then has to be denatured by adding a poisonous substance. Laws like this are written to make sure the “proper” amount of tax is paid on the alcohol, depending on how it is to be used. Fuel alcohol is taxed at a much lower rate than the fun kind.
Drinking Alcohol
Unless you're a moonshiner with a still hidden in the woods, it's cheaper and easier to buy your drinking goods and store them. I don't drink hard liquor, but I keep a few bottles on hand for guests and as potential trade goods. Small bottles fit my needs best, since they take up little space and, like silver, make for good “small denominations” when making change. Even a few of the airline-sized bottles would come in handy for cleaning a wound or trading for small items. This is obviously a “bugging in” or cache item. Every once of weight in a backpack will make itself known once you start to carry it.
Making safe-to-drink alcoholic beverages is an old art that predates science and agriculture and isn't hard -- if bread, water, and fruit can be turned into contraband wine in prisons, how hard can it be? -- but it takes time, equipment, and money. Since 1978, the Federal Government has allowed people the privilege of producing up to 100 gallons of beer or wine per adult per year for personal consumption without paying taxes on it. State laws vary, but at least you don't have to worry about the BATFE as long as you stay under their limits. Drinking alcohol comes in two types, fermented and distilled.
Beer, wine, cider, and mead are the main fermented forms of alcohol.
Beer is the result of fermentation of cereal grains followed by the addition of hops, which act as a preservative.
- Since the sugar content of grains is fairly low, and the “malting” process of converting starches to sugars is dependent on the enzymes available, most beer yeasts produce 4-6% alcohol. This is not quite enough alcohol to kill off other microbes, so hops are added as a preservative.
- Barley, oats, rice and wheat are the main grains used in making beer around the world.
- Simple beer is nothing more than barley, water, yeast and hops.
- Beer doesn't store well, and should be consumed within a few months of being made.
- Since the sugar content of fruit is higher than that of grains, it is possible to get a higher alcohol content in wine (generally around 10%), which is high enough to be self-preserving as long as the container stays sealed.
- Wine, if properly stored, can last for centuries.
- I helped put up 60 gallons of Elderberry wine in recycled liquor bottles (free from a bar) about 40 years ago. As long as the lid sealed tight, the wine is still fit to drink and may have actually improved a bit with age. The ones that didn't seal are pretty nasty.
- Often made using wild or native yeast, the taste and quality can vary from batch to batch.
- Like beer, it doesn't store well.
- Since honey has strong anti-microbial properties, making mead involves a few more steps than making beer or wine. Normally, the addition of nutrients and water is required to allow the activity of the yeast.
- Meads run from 8-20% alcohol, and should store at least as well as wine.
Distilled Alcohol
- Distilled drinks include whiskeys, brandies, vodka, schnapps, and other “hard” liquors.
- You can take a wine at 10-12 % alcohol and convert it into a brandy at 35% alcohol by distillation. Instructions for home distilling can be found here.
- Hard liquor is useful as as disinfectant, and if the alcohol content is over 60%, it can be used as a fuel in engines and lamps.
- At roughly 50% it will hold a flame, which is how moon-shiners tested, or “proofed”, their batches: if it would hold a flame, it was 100 Proof. That's how we got the silly “80 Proof” on the labels of our rum, which is 40% alcohol. (Sorry, the chemist in me detests arbitrary measuring systems, and alcohol production is so old that it is full of arbitrary measuring systems.)
Fuel alcohol is taxed and controlled by the federal government, but they have created a “small-scale producer” permit that is fairly easy to obtain. It will allow you to produce up to 5000 gallons of pure alcohol per year, which should be enough for your daily driving.
- Find a source of sugars or starches, be it grain, fruit, or whatever you have at hand that can contribute sugars. There are special tools that will tell you how much sugar is in a solution (measured in Brix).
- Find the enzymes you'll need to break the starches into sugars.“Malting” is simply wetting the grain to allow it to sprout. This releases enzymes that break down the starches for the plant to use. Heating the malted grain stops the sprouting and gets it ready for the yeast.
- Add yeast to start the fermentation. Brewers yeast is best, since it has been bred to be efficient at producing alcohol, but any yeast (even wild yeast floating through the air) will work.
- Keep the yeast happy (manage nutrients, temperature, etc.). This is where you get to control the heat and air. Fermentation is an anaerobic process and must be done in an environment free of oxygen.
- Once the yeast are done converting the sugars to alcohol, run the liquid through a distillation column. Done-ness is normally indicated by the reduction of CO2 being produced by the yeast. Testing the density (specific gravity) of the liquid will tell you how much of it is alcohol. Design of columns is a science, and there are many kits and plans available. A good column will result in 90-95% alcohol, which is good enough to use as fuel. Plans for a 6 inch column can be found here, and it is rated at 6-8 gallons of alcohol per hour.
- Separate the solids for use as high-protein animal feed. You don't lose the grain, just the sugars and starches. It is common to rinse the solids and use the rinsate for the next batch, thereby reusing some of the nutrients. Contrary to claims on the internet, alcohol production does not take grain out of the mouths of children and animals. The Distillers Dry Grain Solids (DDGS) is a great animal feed, and is actually sold to feed-lots and feed producers. Cows, pigs, and chickens love it.
The Fine Print
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